Concerted C−N and C−H Bond Formation in a Magnesium-Catalyzed Hydroamination
نویسندگان
چکیده
منابع مشابه
Baker’s yeast catalyzed Henry reaction: Biocatalytic C-C bond formation
The C-C bond formation is an important reaction in organic synthesis to obtain value-added intermediates. Therefore, in this paper an attempt has been made to accelerate the Henry reaction (C-C bond formation) between aryl aldehydes and nitromethane using less expensive whole cell biocatalyst, baker’s yeast (BY). The scope of the methodology was also tested for the heteryl aldehyde i.e. 2-chlor...
متن کاملBaker’s yeast catalyzed Henry reaction: Biocatalytic C-C bond formation
The C-C bond formation is an important reaction in organic synthesis to obtain value-added intermediates. Therefore, in this paper an attempt has been made to accelerate the Henry reaction (C-C bond formation) between aryl aldehydes and nitromethane using less expensive whole cell biocatalyst, baker’s yeast (BY). The scope of the methodology was also tested for the heteryl aldehyde i.e. 2-chlor...
متن کاملMetal-catalyzed carbon-sulfur bond formation.
In organic synthetic reactions, the scope and application of organosulfur chemistry have increased tremendously since sulfur-containing groups serve an important auxiliary function in synthetic sequences.1 Illustrative examples are the reversal of polarity (Umpolung), the enhancement of the acidity of C-H bonds, and the transfer of chirality from sulfur to carbon.2 On the other hand, transition...
متن کاملCarbon-carbon formation via Ni-catalyzed Suzuki-Miyaura coupling through C-CN bond cleavage of aryl nitrile.
The Suzuki-Miyaura coupling of aryl nitriles with aryl/alkenyl boronic esters is reported. With this method, the cyano group could be applied as a protecting group of arenes and finally as a leaving group to further construct polyaryl scaffolds.
متن کاملA New Palladium-Catalyzed Phenyl-Alkene Bond Formation
A new method of palladium-catalyzed phenyl-alkene bond formation is reported. This reaction involves transfer of all three phenyl groups from triphenylantimony onto alkenes containing allylic protons.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2010
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja108881s